101-68-8 MSDS PDF

), Back Directory. [msds information] 1,1′-Methylenebis(4-isocyanatobenzene)( ).msds. Page 1. Page 2. •. •. •. ³. ³. ³. Page 3. ³. Page 4. ³. ³. ³. ³. ³. ³. ³. ³. ³. ³. Page 5. ≥. ≥. Page 6. METHYLENE BISPHENYL. ISOCYANATE. DOT Number: UN DOT Hazard Class: (Poison). NAERG Code: CAS Number: Hazard rating.

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Methylene diphenyl diisocyanatemost often abbreviated as MDI, is an aromatic di isocyanate.

Three isomers are common, varying by the positions of the isocyanate groups around the rings: The 4,4′ isomer is most widely used, and is also known as 4,4′-diphenylmethane diisocyanate. MDI reacts with polyols in the manufacture of polyurethane.

Methylene diphenyl diisocyanate

It is the most produced diisocyanate, accounting for The largest producer is Wanhua Group followed closely by Covestro. The first step of the production of MDI is the reaction of aniline and formaldehydeusing hydrochloric acid msvs a catalyst to produce a mixture of diamine precursors, as well as their corresponding polyamines:.

Then, these diamines are treated with phosgene to form a mixture of isocyanates, the isomer ratio being determined by the isomeric composition of the diamine. Distillation of the mixture gives a mixture of oligomeric polyisocyanates, known as polymeric MDIand a mixture of MDI isomers which has a low 2,4′ isomer content. Further purification entails fractionation of the MDI isomer mixture. The positions of the isocyanate groups influences their reactivity.

In 4,4′-MDI, the two isocyanate groups are equivalent but in 2,4′-MDI the two groups display highly differing msfs. The group at the 4-position is approximately four times more reactive than the group at the 2-position due to steric hindrance.

The major application of 4,4′-MDI is the production of rigid polyurethane.

Methylene bisphenyl isocyanate

Typical polyols used are polyethylene adipate a polyester and poly tetramethylene ether glycol a polyether. MDI is the least hazardous of the commonly available isocyanates but is not benign. However, it, like the other isocyanates, is an allergen and sensitizer.

Persons developing sensitivity to isocyanates may have dangerous systemic reactions to extremely small exposures, including respiratory failure. Handling MDI requires strict engineering controls and personal protective equipment.

It is a potentially violently reactive material towards water and other nucleophiles. From Wikipedia, the free encyclopedia.

CDC – NIOSH Pocket Guide to Chemical Hazards – Methylene bisphenyl isocyanate

Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI. Interactive image Interactive image. LD 50 median dose. LD Lo lowest published.

4,4′-Methylenediphenyldiisocyanate | C15H10N2O2 – PubChem

LC 50 median concentration. Toluene diisocyanate Naphthalene diisocyanate Hexamethylene diisocyanate Isophorone diisocyanate. Eco-Profiles of the European Plastics Industry. Archived from the original PDF on Safety, Health and the Environment: A Source Book and Practical Guide. Retrieved from ” https: Views Read Edit View history.

This page was last edited on 10 Augustat By using this site, you agree to the Terms jsds Use and Privacy Policy. Other names Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI.

Lethal dose or concentration LDLC:.


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El libro de las quimeras

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El Ocaso del Pensamiento

Some of these are collections of brief essays one or two pages, on average ; others are collections of aphorisms. Influenced by the German romantics, by Schopenhauer, Nietzsche and the Lebensphilosophie of Schelling and Bergson, by certain Russian writers, including Chestov, Rozanov, and Dostoyevsky, and by the Romanian poet Eminescu, Cioran wrote lyrical and expansive meditations that were often metaphysical in nature and whose recurrent themes were death, despair, solitude, history, music, saintliness and the mystics cf.

Tears and Saints, — all of which are themes that one finds again in his French writings. After spending two years in Germany, Cioran ciogan in Paris in He continued to write in Romanian until the early s he wrote his last article in Romanian inwhich is also the year in which he began writing in French.

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We report a case of primary cutaneous infection by the emerging fungus Aspergillus ustus in an immunosuppressed patient after a domestic accident. Aspergillus ustus is a mold that rarely infects humans; only 15 systemic cases have been reported. We report the first outbreak of invasive infection caused by A . Med Mycol. Jun;45(4) Clustering of invasive Aspergillus ustus eye infections in a tertiary care hospital: a molecular epidemiologic study of an.

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Aspergillus ustus is a mold that rarely infects humans; only 15 systemic cases have been reported. We report the first outbreak of invasive infection caused by A. Six patients with infections were identified; 3 infections each occurred in both and Molecular typing aspergilus using randomly amplified polymorphic DNA RAPD and antifungal drug susceptibility testing were performed on clinical and environmental isolates recovered from our hospital from to The highest overall attack rate in HSCT patients was 1.

Clinical isolates exhibited decreased susceptibility to antifungal drugs, especially azoles. RAPD and phylogenetic analysis showed genetic similarity between isolates from different patients. Based on the clustering of cases in space and time and molecular data, common-source acquisition of this unusual drug-resistant species is possible. The most common cause of IA is Aspergillus fumigatus 2. However, in recent years, IA has been increasingly caused by non- fumigatus Aspergillus species.

For example, at the Fred Hutchinson Cancer Research Center in Seattle, the proportion of infections caused by non- fumigatus Aspergillus species increased during the latter s.

Most of these infections were caused by A. Aspergillus ustus is a group of filamentous hyalohyphomycetes consisting of 5 species: Members of this xspergillus are rare human pathogens; only 15 cases of systemic infection have been reported in the literature sinceand more than half of these occurred in the past 10 years Table A1 4 – Infections caused by A.

Recognition of invasive infections that occurred in 2 clusters of hematopoietic apsergillus cell transplant HSCT recipients in our institution prompted us to perform a more thorough clinical investigation and environmental sampling to identify potential sources of acquisition.

Recognition of time-clustered cases in prompted us to do this retrospective study and epidemiologic investigation. Cases of infection caused by A.

Aspergillus ustus

Charts were reviewed for clinical data demographics, underlying disease, transplantation characteristics, antifungal therapies, radiographic and laboratory studies, and outcome. The hospital is a large tertiary care facility that houses patients with HSCT on the top 2 floors the northeast wings of the seventh and eighth floors. A spot map depicting case-patient location and timeline relating location to time of diagnosis was created.

Information on timing of construction activities and airflow information was obtained from hospital engineering and infection control personnel. An attack rate was estimated among the potentially exposed HSCT patients using as the denominator the number of patients who were admitted for HSCT from July through October and March through Septemberthe at-risk periods when cases occurred.

Based on the spot map, environmental air sampling of patient hospital rooms was performed, and environmental isolates were obtained. Organisms were identified to the species level by using standard morphologic criteria for A.

Ustys typing of A. Aspergiplus were subjected to 3 cycles of freeze-thaw in liquid nitrogen, alternating with vortexing with 0. PCR products underwent electrophoresis in 1. The band patterns from each gel with each primer were analyzed by using tools for population genetics analysis TFPGA unpub.

Cluster analysis was performed by the unweighted pair group mean with arithmetic average UPGMA method Antifungal drug susceptibility testing of A. Susceptibility minimal effective concentration to caspofungin Merck Research Laboratories, Rahway, NJ, USA was determined by using a microbroth dilution assay in antibiotic 3 AM3 media, as described previously We identified 2 clusters of A.

The first occurred from July to October 3 probable lung infections: The second occurred from March to September 1 proven skin infection [likely disseminated from lung] and 2 probable lung infections: The median age of patients was 59 range 29 years; 5 Estimating that patients were admitted for HSCT during ustuw at-risk period, the highest overall attack rate was 1.

No changes in laboratory processing or mold identification methods occurred during the study. Of note, construction of a new surgery pavilion occurred outside our hospital building beginning in July and ending in December The spot map and time line showed that cases clustered mainly along 2 corridors on 2 floors, 1 directly above the other, around the time of diagnosis. In the and outbreaks, all case-patients resided in the same or adjacent rooms before diagnosis Figure 1.

Spot map illustrating case-patient location on the northwestern wing of the eighth floor 8NE and the seventh floor 7NE from the left panel and outbreaks right panel at the time of case diagnosis. Patient 3 was in the outpatient clinic at aspsrgillus time of diagnosis and is, therefore, not marked on this inpatient kstus map.

Patient 5 and 6 resided in the same room at different times. Patients aspergkllus, 4, 5, and 6 were moved to a variety of rooms around the time of diagnosis as indicated by their location in multiple rooms. Environmental air sampling performed aslergillus months after the last case occurred in found no A. The same bronchoscope was used to evaluate each patient; however, it was usrus after each examination.

Also, several patients who were not found to have A. One patient patient 3 did not have a viable isolate stored, and 1 patient patient 5 had 3 isolates recovered during the course of infection. A total of 73 bands were resolved from the 11 A.

The asspergillus recovered from the 5 HSCT were genetically similar. Three isolates from patient 5 were genetically most similar to the isolate from patient 2. At the time of his diagnosis and death, patient 2 resided in a room directly adjacent to and above the room of patient 5, albeit 2 years earlier Figure 1.

Similarly, the isolate from patient 1 was genetically most similar to that of patient 4; patients 1 and 4 resided in adjacent rooms, also separated by a period of 2 years. Of note, the lung transplant patient appeared to be colonized with a strain of A. Antifungal drug susceptibility testing of clinical isolates demonstrated relatively high MICs to all antifungal drugs tested Table 2. Molecular typing of Aspergillus ustus isolates by using random amplification of sutus DNA. The isolate from patient 3 was not viable on subculturing and, as such, was not available for molecular analysis.

Gel images A and composite dendrogram B are shown. We report the first outbreak of disease caused by an unusual fungal pathogen, A. This observation is important, given the possibility of common-source acquisition of a potentially antifungal drug—resistant organism. All members of the A. Macroscopically, the colonies appear drab olive to dull brown or gray and woolly with occasional dark purple or yellow exudates. Microscopically, the conidia are large 3. Although these toxins may be medically important, the quantities of toxin produced in the environment may not be significant 28 The spectrum of disease reported due to A.

All previously reported cases occurred sporadically in diverse medical centers Table A1. Many reported cases have been either primary cutaneous disease or disseminated infection, however, we cannot draw firm conclusions regarding the types of infections this organism causes because of the high likelihood of reporting bias. The relative pathogenicity of this Aspergillus species has not been well studied.

These patients also possessed classic risk factors for IA in that most had graft-versus-host disease that required corticosteroid and other immunosuppressive therapy Overall death rates of patients with A. Whether death was attributable to the fungal infection, coinfections, or underlying diseases is unclear.

A common source for the A. Since these patients resided in rooms within close proximity, common source acquisition e. Common source acquisition may not be precluded by case isolate separation in time as Aspergillus conidia are resistant to harsh conditions, surviving in the environment for many years in dormant phase However, the environmental niche of this fungus is not known.

Patients were in and out of the hospital after transplantation, so infection could have been acquired in the environment. We also cannot rule out the possibility that other clinical factors e. The results of molecular analyses suggest genetic similarity of isolates recovered from patients. Although discriminatory power of RAPD analyses has some limitations 33 usuts, the composite analysis demonstrated large separations between patient isolates and the control ATCC strain.

Our study is limited by the lack of local environmental A. Although the clinical isolates appear different from the ATCC strain, the genetic similarity of case strains may ustux a strain common to our local environment. Also, these analyses are limited by our lack of uztus concerning A. Specifically, genomic rearrangement with recombination, which has been postulated to occur in several species of As;ergillusmay increase the variation observed between related strains Our investigation was limited by constraints in conducting retrospective analyses.

More timely environmental sampling may have captured more environmental A.

Aspergillus ustus | Aspergillus & Aspergillosis Website

For example, swabbing of dust-ridden surfaces may have indicated the underlying air quality in terms of fungal spores in the preceding months when infection may have occurred.

In the absence of substantial air disturbances, A. Construction, a well-known environmental risk factor for IA 36was ongoing outside the hospital during the time of these outbreaks.

We cannot comment on the role of water as a source of infection, which has been reported in multiple hospitals 32 Determining the source of infection is further complicated in that a combination of inoculum effect and underlying host immunosuppression make calculating the incubation period problematic. Thus, the source of A. These outbreaks of A.

Although we do not know breakpoints of A. Most of our patients received mold-active azole drugs before diagnosis as either prophylaxis or therapy for a previous infection with A. Drug exposure may select for colonization or infection with resistant isolates or facilitate acquired resistance within a colonizing strain.

The latter may occur in A. In this cohort, several patients who received the combination regimen of voriconazole and caspofungin had A. A combination of factors, including severity of underlying host immunosuppression and common source acquisition, likely played a role in the reported outbreaks.


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Results 1 to jlb of Is this a “horn” -driver? The is also used in the larger Sythesis Systems too. Its a nice sounding driver.

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Ok, nice to hear from you! Ahh, i do not know how to say this in english, is it called “dispersion”? Well the smaller the driver the better the dispersion as long as the driver is clean and not in break up modes depending on how high you plan to cross it over.

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It does well up to the 3k crossover in the You won’t be going that high with it as a midrange?? I am trying to figure out how to design horns.

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And then there is also the cone breakups to consider For example the used in in the 8″ CMCD design has a break mass point of Hz very highand is used past 2khz in many current JBL designs together with a jgl plug. Jbl used the M in a horn.

They had some in the tent sale a few guys managed to get them http: Originally Posted by pos. So for the H it is: Mobile JBL almost ready By johnaec in forum General Audio Discussion.

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